Initial Rate Equation:
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The initial rate of reaction (v0) is the rate at which reactants are converted to products at the very beginning of a chemical reaction. It's determined by the rate constant, reactant concentrations, and the reaction order.
The calculator uses the initial rate equation:
Where:
Explanation: The equation shows how the initial rate depends on the concentration of reactants raised to the power of their reaction order, multiplied by the rate constant.
Details: Calculating initial rates helps determine reaction kinetics, understand reaction mechanisms, and predict how changes in conditions will affect reaction speed.
Tips: Enter the rate constant (with appropriate units for your reaction order), initial reactant concentration in molarity (M), and the overall reaction order. All values must be positive numbers.
Q1: What are typical units for the rate constant?
A: Units vary with reaction order: 1st order (s-1), 2nd order (M-1s-1), 0th order (M/s).
Q2: How is reaction order determined?
A: Experimentally by measuring how initial rate changes with concentration changes, or theoretically from the reaction mechanism.
Q3: Why measure initial rates specifically?
A: Initial rates eliminate complications from product accumulation, reverse reactions, or changing reactant concentrations.
Q4: Can this be used for complex reactions?
A: For reactions with multiple reactants, each reactant's concentration and order must be considered in the rate law.
Q5: How does temperature affect the rate?
A: Temperature affects the rate constant (k) according to the Arrhenius equation, but not the reaction order.