Second Order Reaction Rate Equation:
From: | To: |
The initial rate of reaction (v0) is the rate at which a chemical reaction proceeds at the very beginning, when the concentrations of reactants are known and products have not yet accumulated. For a second-order reaction with two reactants, the rate depends on the product of the concentrations of both reactants.
The calculator uses the second-order reaction rate equation:
Where:
Explanation: The equation shows that the initial rate is directly proportional to both the rate constant and the product of the initial concentrations of the two reactants.
Details: Calculating the initial rate is crucial for understanding reaction kinetics, determining reaction orders, and designing chemical processes. It helps chemists predict how fast a reaction will proceed under specific conditions.
Tips: Enter the rate constant in M-1s-1, initial concentrations in molarity (M). All values must be positive numbers. The calculator will compute the initial rate in mol/s.
Q1: What is a second-order reaction?
A: A second-order reaction is one whose rate depends on the concentration of two reactants or the square of one reactant's concentration.
Q2: What are typical units for second-order rate constants?
A: For reactions with two different reactants, the rate constant typically has units of M-1s-1.
Q3: Why measure initial rates?
A: Initial rates eliminate complications from reverse reactions, product inhibition, or changing reactant concentrations that occur as the reaction progresses.
Q4: How is this different from first-order reactions?
A: First-order reactions depend only on one reactant's concentration (rate = k[A]), while second-order reactions depend on two reactants' concentrations.
Q5: Can this be used for elementary reactions only?
A: This form applies to elementary bimolecular reactions. For complex reactions, the rate law must be determined experimentally.