General Rate Law:
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The rate law expresses the rate of a chemical reaction as a function of the concentrations of the reactants. It takes the general form: Rate = k [A]m[B]n..., where k is the rate constant, [A], [B] are concentrations, and m, n are the reaction orders.
The calculator uses the general rate law equation:
Where:
Explanation: The rate law shows how the reaction rate depends on reactant concentrations, with the exponents representing the reaction order for each reactant.
Details: The rate law is fundamental in chemical kinetics, helping predict reaction rates under different conditions, design chemical reactors, and understand reaction mechanisms.
Tips: Enter the rate constant (with appropriate units), reactant concentrations in molarity (M), and reaction orders. You can calculate rates for reactions with up to two reactants.
Q1: How do I determine the reaction orders?
A: Reaction orders must be determined experimentally, typically through initial rates method or integrated rate laws.
Q2: What are typical units for rate constants?
A: Units vary with overall reaction order: M1-ns-1, where n is the overall order.
Q3: What's the difference between rate and rate constant?
A: The rate constant (k) is a proportionality factor, while rate depends on both k and reactant concentrations.
Q4: Can this calculator handle zero-order reactions?
A: Yes, just enter 0 as the reaction order for a particular reactant.
Q5: What about complex reaction mechanisms?
A: This calculator handles elementary reactions. Complex mechanisms may require more sophisticated analysis.